Highly regioselective α-alkylation of α,β,γ,δ-unsaturated aldehydes

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dc.contributor.author Padmaja, Venkata M. D.
dc.contributor.author Jangra, Sachin
dc.contributor.author Appayee, Chandrakumar
dc.date.accessioned 2018-09-22T09:56:52Z
dc.date.available 2018-09-22T09:56:52Z
dc.date.issued 2018-09
dc.identifier.citation Padmaja, Venkata M. D.; Jangra, Sachin and Appayee, Chandrakumar, "Highly regioselective ?-alkylation of ?,?,?,?-unsaturated aldehydes", Organic & Biomolecular Chemistry, DOI: 10.1039/C8OB02059K, Sep. 2018. en_US
dc.identifier.issn 1477-0520
dc.identifier.issn 1477-0539
dc.identifier.uri https:/doi.org/10.1039/C8OB02059K
dc.identifier.uri https://repository.iitgn.ac.in/handle/123456789/3903
dc.description.abstract The first α-alkylation of α,β,γ,δ-unsaturated aldehydes is achieved under mild reaction conditions. Several α,β,γ,δ-unsaturated aldehydes and diarylcarbinols are successfully tested for the synthesis of MBH-type α-alkylated products with an excellent regioselectivity. Simple pyrrolidine is efficiently used as a catalyst to achieve a perfect E/Z selectivity of the α-alkylated products.
dc.description.statementofresponsibility by Venkata M. D Padmaja,, Sachin Jangra and Chandrakumar Appayee
dc.language.iso en en_US
dc.publisher Royal Society of Chemistry Publishing en_US
dc.subject ?-alkylation of ?,?,?,?-unsaturated aldehydesunsaturated aldehydes en_US
dc.subject diarylcarbinols en_US
dc.subject Synthesis of MBH-type ?-alkylated products en_US
dc.title Highly regioselective α-alkylation of α,β,γ,δ-unsaturated aldehydes en_US
dc.type Article en_US
dc.relation.journal Organic & Biomolecular Chemistry


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