Methane Oxidation by Lanthanum Oxide Doped with Cu, Zn, Mg, Fe, Nb, Ti, Zr, or Ta: The Connection Between the Activation Energy and the Energy of Oxygen-Vacancy Formation

Methane Oxidation by Lanthanum Oxide Doped with Cu, Zn, Mg, Fe, Nb, Ti, Zr, or Ta: The Connection Between the Activation Energy and the Energy of Oxygen-Vacancy Formation

Derk, Alan R.; Li, Bo; Sharma, Sudhanshu; Moore, George M.; McFarland, Eric W.; Metiu, Horia
URI: http://dx.doi.org/10.1007/s10562-013-0985-7
https://repository.iitgn.ac.in/handle/123456789/889
Date: 2013-05

Abstract:

We measure the effective activation energy of methane oxidation catalyzed by La2O3 doped with Cu, Zn, Mg, Fe, Nb, Ti, Zr, or Ta. We find that the measured activation energy is a linear function of the calculated energy of oxygen-vacancy formation.

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