Membrane compaction in batch reverse osmosis operation and its impact on specific energy consumption

Abstract

Reverse osmosis (RO) membrane water permeability is measured under cyclic pressure loading conditions corresponding to batch and semi-batch operation modes. Due to the viscoelasticity of the membrane support layer, compaction effects carry forward across multiple pressurization cycles, with the intracycle behavior stabilizing after a large number of cycles. The average membrane permeability of semi-batch RO systems is lower than that of batch RO, since semi-batch RO spends a larger fraction of its cycle time at higher pressures. The instantaneous permeability in batch RO decreases during the cycle as pressure is increased, but at a lower rate than the steady-state permeability variation with applied pressure. Therefore, the batch permeability values are lower at low pressures and higher at high pressures than the corresponding steady-state values. Since more water is recovered in the initial low-pressure stages of a multi-stage RO system, compaction increases the specific energy consumption of batch RO more than that of staged systems. Other loss mechanisms such as channel and minor pressure losses and high-pressure motor+pump efficiency variation with load further result in batch RO becoming energetically inferior to two- or three-stage RO, especially for low-salinity, high recovery applications.