Abstract:
Extended black hole thermodynamics, or ``black hole chemistry,'' is usually formulated in asymptotically AdS spacetimes by promoting the cosmological constant \Lambda to a thermodynamic variable and identifying P=-\Lambda/8\pi as the pressure. This approach, however, is less physically motivated: \Lambda is a fixed coupling of the bulk action. Moreover, in de Sitter space, the construction is even more problematic due to the absence of a global timelike Killing vector and the presence of multiple horizons. In this work, we show that extended thermodynamics arises naturally in a Dvali-Gabadadze-Porrati (DGP) braneworld once the brane tension \sigma is varied in the Iyer--Wald formalism. A positive-tension brane is dynamically stable, ghost-free, and induces a localized vacuum energy density T^{(\sigma)}_{\mu\nu}=-\sigma g_{\mu\nu}, corresponding to a negative pressure P_\sigma=-\sigma. On the normal branch, the brane is asymptotically flat with a well-defined ADM mass and a single black hole horizon, thereby avoiding the obstructions that arise in de Sitter. We demonstrate that varying \sigma produces a new work term V_\sigma\,\delta P_\sigma in the first law, with V_\sigma reducing exactly to the geometric volume 4\pi r_h^3/3 for a static spherical black hole. The associated Smarr relation is derived, and we show how asymptotic flatness can be maintained along the family of solutions by co-varying the bulk cosmological constant. Our results establish that extended black hole thermodynamics is not restricted to AdS spacetimes but also arises consistently in asymptotically flat braneworlds through brane tension, providing a new setting for black hole chemistry.