Transverse correlations near solid-liquid interface: Influence of the crystal structure of solid

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dc.contributor.author Chouksey, Shubham
dc.contributor.author Rane,Kaustubh
dc.date.accessioned 2018-11-02T07:55:35Z
dc.date.available 2018-11-02T07:55:35Z
dc.date.issued 2019-01
dc.identifier.citation Chouksey, Shubham and Rane, Kaustubh, "Transverse correlations near solid-liquid interface: Influence of the crystal structure of solid", Chemical Physics, DOI: 10.1016/j.chemphys.2018.10.017, vol. 517, pp. 188-197, Jan. 2019. en_US
dc.identifier.uri https://doi.org/10.1016/j.chemphys.2018.10.017
dc.identifier.uri https://repository.iitgn.ac.in/handle/123456789/3985
dc.description.abstract Transverse correlations (TCs) denote the correlations between density-fluctuations along the plane parallel to a solid-liquid interface. We use molecular simulations to investigate the TCs in a model fluid near static 100, 110 and 111 faces of BCC, FCC, and SC crystals of model solids. We use the cumulant expansions of solid-liquid interfacial free energies to quantify the contribution of TCs to the interfacial free energy. We approximately decompose the above contributions into those from TCs of different ranges. Our results show that the solid-fluid attractive interaction strongly dampens the TCs, and the extent of dampening depends on the exposed face of the crystal. We also observe that the contribution from TCs near the selected surfaces differ significantly even in absence of solid-fluid attractive interaction. Overall, our results indicate a great potential for tuning the solid-liquid interfacial fluctuations by altering the crystalline nature of solid surface.
dc.description.statementofresponsibility by Shubham Chouksey and Kaustubh Rane
dc.format.extent pp.188-197
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.subject Transverse correlations en_US
dc.subject solid-liquid interface en_US
dc.subject crystal structure of solid en_US
dc.title Transverse correlations near solid-liquid interface: Influence of the crystal structure of solid en_US
dc.type Article en_US
dc.relation.journal Chemical Physics


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