Abstract:
Elevated ozone (O3) near the earth's surface causes adverse impacts on human health and vegetation, besides impacting air chemistry and climate. Intense lockdown to contain the spread of Coronavirus disease 2019 (COVID-19) offered a rare opportunity to delineate the anthropogenic impact on urban O3 build-up. In this regard, we incorporated observations of chemical species and environmental conditions into a photochemical box model (NCAR Master Mechanism) to study the O3 changes at a semi-arid urban site in western India (Ahmedabad; 23'N, 72.6'E). In contrast with primary pollutants, daytime O3 build-up is observed to be enhanced during the lockdown by ~39%. Model, driven by lower nitrogen oxides (NOx) during the lockdown, also simulated enhanced O3 (by ~41%) showing the role of nonlinear dependence of O3 on NOx. Further, a sensitivity simulation unravelled an important role of the meteorological changes in the O3 enhancement (by ~16%) during the lockdown. The results highlight that the lockdown impacts can be modulated profoundly by the complex chemistry plus meteorological changes, offsetting the benefits of lower precursor levels in the context of O3 pollution.