Versatility of Surfactant-Mediated NiTe2 Nanoparticles: Unlocking Potential for Hydrogen Evolution Reaction, Supercapacitor, and Sustainable Green Catalysis
Source
Small
ISSN
16136810
Date Issued
2025-10-23
Author(s)
Mathur, Neha
Choudhary, Monu
Dwivedi, Abhinav Kashyap
Nama, Jatin
Shwetha, K. P.
Manjunatha, C.
Shama, Sudhanshu
Gupta, Pankaj
Joshi, Hemant
Abstract
Designing multifunctional nanomaterials is economically and practically advantageous. Herein, this work reports a surfactant-mediated synthesis of NiTe<inf>2</inf> nanoparticles (NPs) and their applications in electrocatalysis, energy storage, and sustainable green catalysis. The NiTe<inf>2</inf> NPs exhibit excellent hydrogen evolution reaction (HER) activity, with a low overpotential of 309 mV versus RHE at 10 mA cm<sup>−2</sup> and a Tafel slope of 50 mV dec<sup>−1</sup>, indicating fast kinetics. As supercapacitor (SC) electrodes, they deliver a high specific capacitance of 620 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, retaining 62% at 10 A g<sup>−1</sup> and 78.3% after 5000 cycles. An asymmetric coin cell (ASC) achieves 75.3 F g<sup>−1</sup> specific capacitance, 30.6 Wh kg<sup>−1</sup> energy density, and 914.6 W kg<sup>−1</sup> power density, with 76.4% capacitance retention and 93.7% efficiency after 5000 cycles. Additionally, NiTe<inf>2</inf> NPs enable the sustainable synthesis of quinolines and 2-aminoquinolines, achieving up to 97% yield under mild conditions with only 0.00563 mmol (in 10 mg) catalyst loading. These results underscore the versatility of NiTe<inf>2</inf> NPs as a cost-effective, high-performance material for clean energy and green chemistry applications.
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