Spontaneous hydrogen production using Gadolinium Telluride
ISSN
2573-2293
Date Issued
2021-11-01
Author(s)
Tiwary, Chandra Sekhar
Kumbhakar, Partha
Parui, Arko
Dhakar, Shikha
Paliwal, Manas
Behera, Rakesh
Gautam, Abhay Raj Singh
Roy, Soumyabrata
Ajayan, P. M.
Sharma, Sudhanshu
Singh, Abhishek K.
Abstract
Developing a catalyst for green hydrogen production through water splitting, is one of the most promising ways to meet current energy demand. Here, we demonstrate spontaneous water splitting using gadolinium telluride (GdTe) with high hydrogen evolution rate. The spent catalyst can be reused after melting, which regains the original activity of the pristine sample. The phase formation and reusability are supported by the thermodynamics calculations. The theoretical calculation reveals ultra-low over-potential for hydrogen evolution reaction of GdTe caused by charge transfer from Te to Gd, hence enhancing the catalytic activity. Production of highly pure and instantaneous hydrogen by GdTe could accelerate fuel cell-based sustainable technologies.
Subjects
Hydrogen production
Water splitting
Gadolinium telluride
Thermodynamics calculations
