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  5. Versatility of Surfactant-Mediated NiTe2 Nanoparticles: Unlocking Potential for Hydrogen Evolution Reaction, Supercapacitor, and Sustainable Green Catalysis
 
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Versatility of Surfactant-Mediated NiTe2 Nanoparticles: Unlocking Potential for Hydrogen Evolution Reaction, Supercapacitor, and Sustainable Green Catalysis

Source
Small
ISSN
16136810
Date Issued
2025-10-23
Author(s)
Mathur, Neha
Choudhary, Monu
Dwivedi, Abhinav Kashyap
Nama, Jatin
Shwetha, K. P.
Manjunatha, C.
Shama, Sudhanshu
Gupta, Pankaj
Joshi, Hemant
Roy, Partha  
DOI
10.1002/smll.202507377
Volume
21
Issue
42
Abstract
Designing multifunctional nanomaterials is economically and practically advantageous. Herein, this work reports a surfactant-mediated synthesis of NiTe<inf>2</inf> nanoparticles (NPs) and their applications in electrocatalysis, energy storage, and sustainable green catalysis. The NiTe<inf>2</inf> NPs exhibit excellent hydrogen evolution reaction (HER) activity, with a low overpotential of 309 mV versus RHE at 10 mA cm<sup>−2</sup> and a Tafel slope of 50 mV dec<sup>−1</sup>, indicating fast kinetics. As supercapacitor (SC) electrodes, they deliver a high specific capacitance of 620 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, retaining 62% at 10 A g<sup>−1</sup> and 78.3% after 5000 cycles. An asymmetric coin cell (ASC) achieves 75.3 F g<sup>−1</sup> specific capacitance, 30.6 Wh kg<sup>−1</sup> energy density, and 914.6 W kg<sup>−1</sup> power density, with 76.4% capacitance retention and 93.7% efficiency after 5000 cycles. Additionally, NiTe<inf>2</inf> NPs enable the sustainable synthesis of quinolines and 2-aminoquinolines, achieving up to 97% yield under mild conditions with only 0.00563 mmol (in 10 mg) catalyst loading. These results underscore the versatility of NiTe<inf>2</inf> NPs as a cost-effective, high-performance material for clean energy and green chemistry applications.
URI
http://repository.iitgn.ac.in/handle/IITG2025/33814
Keywords
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